Formic Acid → N-Hexylheptyl-formamide

HRID 1938789ノート

反応式

HRID 1938789 の反応式
C([CH:7]([NH2:14])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])CCCCC.[CH:15]([OH:17])=O>>[CH2:7]([N:14]([CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH:15]=[O:17])[CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

参加物

3

反応物 2

HCID 284Formic AcidHCID 574991Tridecan-7-amine

生成物 1

HCID 53964080N-Hexylheptyl-formamide

実験手順

20.0 g (100 mmol) of 1-hexylheptylamine are heated under reflux with 20.0 g (400 mmol) of 92 percent formic acid for 1 hour. The excess formic acid is distilled off over a 10 cm Vigreux column and the reaction product which remains is subjected to fractional distillation in vacuo. Yield 18.1 g (79%)--boiling point 165° C. (1 mm Hg)-nD 20=1.4577. The reaction product contains a small content of bisformamide which can be removed by distillation only with difficulty but does not interfere in the further reactions.

後処理

  1. distillationThe excess formic acid is distilled off over a 10 cm Vigreux column
  2. distillationthe reaction product which remains is subjected to fractional distillation in vacuo
  3. customcan be removed by distillation only with difficulty

出典と根拠

ORDレコード
ord-63e2173937f04fb29f3c811c20109631
出典データセット
uspto-grants-1997_12
特許番号
US05693808

反応ノート

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