関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 2-Heptanol | HCID 10976 | — |
| 反応物 | Ethyl 2-(pyridin-2-yloxy)acetate | HCID 21464941 | — |
| 触媒 | Titanium isopropoxide | HCID 11026 | — |
| 生成物 | (1-Methyl)hexyl 2-pyridyloxyacetate | HCID 21464939 | 90% |
反応手順
5.0 g (28 mmol) of ethyl 2-pyridyloxyacetate were suspended in 100 ml of 2-heptanol, 1 ml of titanium tetraisopropoxide were added, and the mixture was stirred for 4 hours at 120° C. The excess 2-heptanol was subsequently distilled off under an oil pump vacuum, and the residue was purified by column chromatography. 6.2 g (90% of theory) of (1-methyl)hexyl 2-pyridyloxyacetate were obtained as a colorless oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05698539 |
|---|
| 出典データセット | uspto-grants-1997_12 |
|---|
| ORD ID | ord-240782b943054781b8e440bec68b2785 |
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| 出典メモ | uspto-grants-1997_12 |
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