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(E)-1-(4-chlorophenyl)-2-(1,2,4-triazol-1-yl)-4,4-dimethyl-1-penten-3-one → Diniconazole
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | (E)-1-(4-chlorophenyl)-2-(1,2,4-triazol-1-yl)-4,4-dimethyl-1-penten-3-one | HCID 10913254 | — |
| 反応物 | (E)-1-(2,4-dichlorophenyl)-2-(1,2,4-triazol-1-yl)-4,4-dimethyl-1-penten-3-one | HCID 11110117 | — |
| 反応物 | (S)-2-amino-1,1-diphenyl4-methylpentan-1-ol hydrochloride | HCID 13036360 | — |
| 反応物 | (S)-2-Amino-3-methyl-1,1-diphenylbutan-1-ol hydrochloride | HCID 18638009 | — |
| 反応物 | (S)-2-amino-1,1-dibenzylpropan-1-ol hydrochloride | HCID 67707195 | — |
| 反応物 | (S)-2-Amino-1,1-diphenylpropan-1-ol hydrochloride | HCID 67707196 | — |
| 反応物 | (S)-2-amino-3-phenylpropan-1-ol hydrochloride | HCID 69017766 | — |
| 生成物 | Diniconazole | HCID 6436605 | — |
反応手順
Reaction was carried out in the same manner as in Example 1 except that (E)-1-(4-chlorophenyl)-2-(1,2,4-triazol-1-yl)-4,4-dimethyl-1-penten-3-one was replaced by (E)-1-(2,4-dichlorophenyl)-2-(1,2,4-triazol-1-yl)-4,4-dimethyl-1-penten-3-one, and that (S)-2-amino-1,1-diphenyl-4-methylpentan-1-ol hydrochloride was replaced by (S)-2-amino-1,1-diphenylpropan-1-ol hydrochloride, (S)-2-amino-1,1-diphenyl-3-methylbutan-1-ol hydrochloride, (S)-2-amino-1,1-dibenzylpropan-1-ol hydrochloride and (S)-2-amino-3-phenylpropan-1-ol hydrochloride, to obtain (+)-(E)-1-(2,4-dichlorophenyl)-2-(1,2,4-triazol-1-yl)-4,4-dimethyl-1-penten-3-ol. The results were summarized in Table 2.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05698742 |
| 出典データセット | uspto-grants-1997_12 |
| ORD ID | ord-570c2e555c7c422da35b8f1689798db0 |
| 出典メモ | uspto-grants-1997_12 |