Dithioerythritol → 6-Deoxyallitol

HRID 1941744

反応式

HRID 1941744 の反応式
[CH3:1][C:2]([C@H:4]([C@H:6]([C@H:8]([CH2:10][OH:11])[OH:9])[OH:7])[OH:5])=[O:3].CC([C@@H]([C@H]([C@H](CO)O)O)O)=O.C(S)[C@@H](O)[C@@H](O)CS>>[CH3:1][C@H:2]([C@H:4]([C@H:6]([C@H:8]([CH2:10][OH:11])[OH:9])[OH:7])[OH:5])[OH:3]

参加物

4

反応物 3

HCID 439352DithioerythritolHCID 22820975(3R,4S,5S)-3,4,5,6-tetrahydroxyhexan-2-oneHCID 86641207HCID 86641207、化合物

生成物 1

HCID 1252806-Deoxyallitol

実験手順

1-Deoxy L-psicose prepared via a reaction of 1-deoxy L-fructose with DTE was reduced to obtain 1-deoxy L-allitol, which was then oxidized microbially (IK7), to produce 6-deoxy D-psicose. 1-Deoxy D-psicose thus obtained reacted with DTE. The reaction conditions are as follows.

出典と根拠

ORDレコード
ord-0e361772d189481b8e0b4651e20f9776
出典データセット
uspto-grants-2013_03
特許番号
US08389248B2

関連ノート

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