1-Octanol → Dicaprylyl Ether
反応式
[CH2:1]([OH:9])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]>C1(C)C=CC=CC=1>[CH2:1]([O:9][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]参加物
3
試薬・触媒・溶媒 1
実験手順
Control Reaction using NAFION 117: From the combination of 0.5 mL 1-octanol (3.17 mmol) and 0.314 g NAFION 117 (0.28 meq (0.89 meq/g)) in 3.0 mL toluene (1.1 M) as solvent was obtained 12.4 mg n-octyl ether (3% isolated yield) upon purification of the crude product (GC ratio of 90:10 (octanol:octyl ether)) by bulb-to-bulb distillation (bp 130° C./3 mm Hg (air bath temp)).
後処理
- customControl Reaction
出典と根拠
- ORDレコード
- ord-79eb8205d7654393a55c306cb567ae2e
- 出典データセット
- uspto-grants-2010_06
- 特許番号
- US07744838B2
反応ノート
読み込み中…