HCID 178504313、化合物 → HCID 178520413、化合物

HRID 1953206ノート

反応式

HRID 1953206 の反応式
[Cl-:1].[Cl-].[CH:3]1([Zr+2:8][C:9]2([CH2:14][CH2:15][O:16][Si](C)(C)C)[CH:13]=[CH:12][CH:11]=[CH:10]2)[CH:7]=[CH:6][CH:5]=[CH:4]1>C1(C)C=CC=CC=1>[Cl-:1].[Cl-:1].[CH:3]1([Zr+2:8][C:9]2([CH2:14][CH2:15][OH:16])[CH:10]=[CH:11][CH:12]=[CH:13]2)[CH:7]=[CH:6][CH:5]=[CH:4]1

参加物

3

反応物 1

HCID 178504313HCID 178504313、化合物

生成物 1

HCID 178520413HCID 178520413、化合物収率 30%

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

2.16 g (5.69 mmol) of the organocomplex (cyclopentadienyl)(trimethylsiloxyethylcyclopentadienyl) zirconium dichloride was added to a suspension of 2.9 g of Silica XPO 2407 in 75 ml of dry toluene at room temperature; the suspension immediately acquired a greenish-yellow color. The sample was maintained under continuous stirring at room temperature for 48 hours. The yellow solution was separated from the solid by filtration. The solution was brought to dryness and, after washing with three fractions of 15 ml of hexane, a dusty white solid was obtained. (0.57 g Yield: 30%) 1H-NMR: (Cl3CD): 1.65 (m,1H), 2.95 (t,2H), 4.05 (m,2H), 6.32 (m,2H), 6.35 (m,2H), 6.5 (s,5H).

後処理

  1. temperatureThe sample was maintained
  2. customThe yellow solution was separated from the solid by filtration
  3. washafter washing with three fractions of 15 ml of hexane
  4. customa dusty white solid was obtained

出典と根拠

ORDレコード
ord-4241ccab23ab417684444a42b9b8d999
出典データセット
uspto-grants-2000_09
特許番号
US06114555

反応ノート

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