(R)-(+)-2,2'-Bis(di(3,5-xylyl)phosphino)-1,1'-binaphthyl → (2S,4S)-(-)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE

HRID 1956950

反応式

CC1C=C(P(C2C=C(C)C=C(C)C=2)C2C=C[C:16]3[C:11](=CC=CC=3)[C:10]=2[C:19]2C3C(=CC=CC=3)C=[CH:21][C:20]=2[P:29]([C:38]2[CH:43]=[C:42](C)[CH:41]=[C:40](C)[CH:39]=2)C2C=C(C)C=C(C)C=2)C=C(C)C=1>CCN(CC)CC>[C:38]1([P:29]([C:20]2[CH:21]=[CH:16][CH:11]=[CH:10][CH:19]=2)[C@H:11]([CH2:10][C@@H:19]([P:29]([C:20]2[CH:19]=[CH:10][CH:11]=[CH:16][CH:21]=2)[C:38]2[CH:43]=[CH:42][CH:41]=[CH:40][CH:39]=2)[CH3:20])[CH3:16])[CH:43]=[CH:42][CH:41]=[CH:40][CH:39]=1

参加物

実験手順

Among these transition metal complexes, preferable ones include [Ru2 Cl4 (DM-BINAP)2 ]NEt3, [Ru2Cl4(OcH-BINAP)2 ]NEt3, [Ru2Cl4 (OcH-DM-BINAP)2 ]NEt3, [RuI(p-cymene)(DM-BINAP)]I, [RuCl(p-cymene)(DM-BINAP)]Cl, [RuBr(p-cymene)(DM-BINAP)]Br, [RuI(benzene)(DM-BINAP)]I, [RuCl(benzene)(DM-BINAP)]Cl, [RuBr(benzene)(DM-BINAP)]Br, [RuI(p-cymene)(OcH-BINAP)]I, [RuCl(p-cymene)(OcH-BINAP)]Cl, [RuBr(p-cymene)(OcH-BINAP)]Br, [RuI(benzene)(OcH-BINAP)]I, [RuCl(benzene)(OcH-BINAP)]Cl, [RuBr(benzene)(OcH-BINAP)]Br, [RuI(p-cymene)(OcH-DM-BINAP)]I, [RuCl(p-cymene)(OcH-DM-BINAP)]Cl, [RuBr(p-cymene)(OcH-DM-BINAP)]Br, [RuI(benzene)(OcH-DM-BINAP)]I, [RuCl(benzene)(OcH-DM-BINAP)]Cl and [RuBr(benzene)(OcH-DM-BINAP)]Br, and still preferable ones include [RU2Cl4 (DM-BINAP )2 ]NEt3, [Ru2Cl4 (OcH-BINAP)2 ]NEt3 and [Ru2 Cl4 (OcH-DM-BINAP)2 ]NEt3.

出典と根拠

ORDレコード: ord-1e835340de344dc99f97893541ddb2e5
出典データセット: uspto-grants-1998_07
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05780692

反応式

参加物

反応物 1

生成物 1

試薬・触媒・溶媒 1

実験手順

出典と根拠

関連ノート