3-(4-Phenylbutoxy)propionaldehyde → 4,4,5,5-Tetrafluoro-6-(3-phenylpropoxy)hexanal

反応式

[F:1][C:2]([F:21])([C:7]([F:20])([F:19])[CH2:8][O:9][CH2:10][CH2:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)[CH2:3][CH2:4][CH2:5][OH:6].C1(CCCCOCCC=O)C=CC=CC=1>>[F:1][C:2]([F:21])([C:7]([F:19])([F:20])[CH2:8][O:9][CH2:10][CH2:11][CH2:12][C:13]1[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1)[CH2:3][CH2:4][CH:5]=[O:6]

参加物

反応物 2

HCID 866583073-(4-Phenylbutoxy)propionaldehyde

HCID 866583114,4,5,5-Tetrafluoro-6-(3-phenylpropoxy)hexan-1-ol

生成物 1

HCID 866583154,4,5,5-Tetrafluoro-6-(3-phenylpropoxy)hexanal

実験手順

Obtained from Intermediate 41 (0.68 g, 2.20 mmol) by the procedure described in Intermediate 13. 4,4,5,5-Tetrafluoro-6-(3-phenylpropoxy)hexanal was obtained (0.32 g, 47%) as oil.

出典と根拠

ORDレコード: ord-1e927064caa04d3396ca1c10f9facf6e
出典データセット: uspto-grants-2013_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08420669B2

反応ノート

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