化工社化工社 化学情報印刷レポート · 研究参考用
2-Chlorocyclohexanone → 2,3-Dimethyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Chlorocyclohexanone | HCID 13203 | — |
| 反応物 | 2,3-Butanedithiol | HCID 548353 | — |
| 生成物 | 2,3-Dimethyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine | HCID 12920054 | 49% |
反応手順
The procedure of Example 1(a) is followed using 2,3-butanedithiol and 2-chlorocyclohexanone to give 5,6,7,8-tetrahydro-2,3-dimethyl-1,4-benzodithian as a greenish oil, b.p. 90°-100°/0.07 mm. Yield 49%. NMR 1.34 (6d), 1.45-2.25 (8m), 2.7-3.1 (2m). IR 2900, 1610, 1435, 1365, 1320, 1115, 795, 690.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US03997323 |
| 出典データセット | uspto-grants-1976_12 |
| ORD ID | ord-8056b03b1f3c4fac88325a493db41bbe |
| 出典メモ | uspto-grants-1976_12 |