2,4-Dinitrobenzenesulfenyl chloride → Sulfide, bis(2,4-dinitrophenyl)

HRID 1973772

反応式

HRID 1973772 の反応式
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13]Cl)([O-:3])=[O:2]>C(O)(=O)C>[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[S:13][C:5]1[CH:6]=[CH:7][C:8]([N+:10]([O-:12])=[O:11])=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2])([O-:3])=[O:2]

参加物

3

反応物 1

HCID 682512,4-Dinitrobenzenesulfenyl chloride

生成物 1

HCID 95960Sulfide, bis(2,4-dinitrophenyl)

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

実験手順

To 1.38 g. of 3-butenyltributyltin was added 0.936 g. of 2,4-dinitrobenzene sulfenyl chloride in 20 ml. glacial acetic acid at steam bath temperature. The reaction mixture was warmed on the steam bath for 20 minutes, poured into ice water and filtered. The mixture was extracted with pentane, dried and recrystallized from ethanol to yield cyclopropylcarbinyl 2,4-dinitrophenyl sulfide; m.p. 80° -81° C. Analysis for C and H confirmed the composition of the reaction product.

後処理

  1. temperatureThe reaction mixture was warmed on the steam bath for 20 minutes
  2. filtrationfiltered
  3. extractionThe mixture was extracted with pentane
  4. customdried
  5. customrecrystallized from ethanol

出典と根拠

ORDレコード
ord-ed8d129d868f415b83b0ed6db7603d49
出典データセット
uspto-grants-1976_12
特許番号
US03998889

関連ノート

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