Allylamine → HCID 21490733、化合物
反応式
[C:1]([OH:13])(=O)[CH2:2][CH:3]1[CH:11]=[CH:10][CH2:9][CH2:8][CH:4]1[C:5]([OH:7])=O.[CH2:14]([NH2:17])[CH:15]=[CH2:16]>>[CH2:14]([N:17]1[C:1](=[O:13])[CH2:2][C:3]2[CH2:11][CH2:10][CH2:9][CH2:8][C:4]=2[C:5]1=[O:7])[CH:15]=[CH2:16]参加物
3
実験手順
A mixture of tetrahydrohomophthalic acid (9.2 g., 0.05 mole) and allylamine (2.8 g., 0.05 mole) is heated by an oil bath until molten for 40 minutes. The mixture solidifies upon cooling, and is recrystallized twice from isopropanol, giving 2-allyl-5,6,7,8-tetrahydroisoquinoline-1,3(2H, 4H)-dione.
後処理
- temperatureis heated by an oil bath until molten for 40 minutes
- temperatureupon cooling
- customis recrystallized twice from isopropanol
出典と根拠
- ORDレコード
- ord-dc18d779806e4351ac8fc00a11e9100e
- 出典データセット
- uspto-grants-1976_12
- 特許番号
- US03998954
反応ノート
読み込み中…