Water → Bis(perfluoro-n-butyl) Sulfide H2O

HRID 1975451

反応式

HRID 1975451 の反応式
O.FC(F)(C(F)(F)F)C(OOC(=O)C(F)(F)C(F)(F)F)=[O:5].C=C.FC(F)=C(F)F.[F:30][C:31]([S:43][C:44]([F:56])([F:55])[C:45]([F:54])([F:53])[C:46]([F:52])([F:51])[C:47]([F:50])([F:49])[F:48])([F:42])[C:32]([F:41])([F:40])[C:33]([F:39])([F:38])[C:34]([F:37])([F:36])[F:35]>>[F:42][C:31]([S:43][C:44]([F:55])([F:56])[C:45]([F:53])([F:54])[C:46]([F:51])([F:52])[C:47]([F:48])([F:49])[F:50])([F:30])[C:32]([F:41])([F:40])[C:33]([F:39])([F:38])[C:34]([F:37])([F:36])[F:35].[OH2:5]

参加物

6

反応物 5

HCID 962WaterHCID 6325EthyleneHCID 8301TetrafluoroethyleneHCID 67743Bis(pentafluoropropionyl) peroxideHCID 22917885Bis(perfluoro-n-butyl) sulfide

生成物 1

HCID 86747578Bis(perfluoro-n-butyl) Sulfide H2O収率 29%

反応条件

温度
59 °C

実験手順

A 400-ml vessel was loaded with 100 mL of deionized water. The pressure vessel was then chilled and maintained around -20° C. while further loading with 5 ml of 0.036M perfluoropropionyl peroxide in bis(perfluoro-n-butyl) sulfide, pulling the air off with a vacuum pump, adding 14 g of ethylene, and finally adding 50 g of tetrafluoroethylene. Polymerization set in during warm up at 59° C. and 892 psi, pressure continuing to drop to 751 psi at 60° C. about 4 hours later. The product was washed with 200 ml of 1:1 methanol:water, filtered, and dried under vacuum, giving 18.7 g of white powder (29%). Under melt indexer conditions, no melt flow was observed at 297° C. with a 15-kg weight.

後処理

  1. temperatureThe pressure vessel was then chilled
  2. customPolymerization
  3. washThe product was washed with 200 ml of 1:1 methanol
  4. filtrationwater, filtered
  5. customdried under vacuum

出典と根拠

ORDレコード
ord-e72e011be9af46218728863670ddae91
出典データセット
uspto-grants-1994_02
特許番号
US05286822

関連ノート

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