Cyano(phenyliodonium) triflate → 5,5-Dimethyl-1,3-hexadiynyl(phenyliodonium) triflate

HRID 1975547

反応式

HRID 1975547 の反応式
[CH3:1][C:2]([CH3:21])([CH3:20])[C:3]#[C:4][C:5]#[C:6][Sn](CCCC)(CCCC)CCCC.[O-:22][S:23]([C:26]([F:29])([F:28])[F:27])(=[O:25])=[O:24].C([I+:32][C:33]1[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=1)#N>>[O-:25][S:23]([C:26]([F:29])([F:28])[F:27])(=[O:24])=[O:22].[CH3:21][C:2]([CH3:1])([CH3:20])[C:3]#[C:4][C:5]#[C:6][I+:32][C:33]1[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=1

参加物

3

反応物 2

HCID 11731636Cyano(phenyliodonium) triflateHCID 19100263(5,5-Dimethyl-1,3-hexadiynyl)tri-n-butylstannane

生成物 1

HCID 867475825,5-Dimethyl-1,3-hexadiynyl(phenyliodonium) triflate収率 84%

実験手順

(5,5-dimethyl-1,3-hexadiynyl)tri-n-butylstannane was reacted with cyano(phenyliodonium) triflate as described in the preceding paragraph, with the product workup according to procedure 1) producing an 84% yield of 5,5-dimethyl-1,3-hexadiynyl(phenyliodonium) triflate.

出典と根拠

ORDレコード
ord-c24db113699b430c98e40d268d29aee8
出典データセット
uspto-grants-1994_02
特許番号
US05286901

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