Phenylacetone → HCID 539743、化合物

HRID 1979505ノート

反応式

[CH2:1]([C:8]([CH3:10])=[O:9])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:11](Cl)[CH:12]=[CH:13][CH3:14].ClC(C)C=C>>[C:2]1([CH:1]([C:8](=[O:9])[CH3:10])[CH2:11][CH:12]=[CH:13][CH3:14])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

反応物 3

HCID 7678Phenylacetone

HCID 112423-Chloro-1-butene

HCID 11589Crotyl chloride

生成物 1

HCID 539743HCID 539743、化合物

実験手順

Methyl benzyl ketone is reacted with crotyl chloride or 3-chloro-1-butene in accordance with the foregoing details and there is obtained 5-phenyl-hept-2-en-6-one of boiling point 88° C./3 mmHg; nD20 =1.5190. When 3-chloro-1-butene is used there is also obtained 3-methyl-5-phenyl-hex-1-en-5-one which is separated by distillation.

出典と根拠

ORDレコード: ord-a11b5eb679c245768a6130720bcc4ac5
出典データセット: uspto-grants-1984_11
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04481133

反応ノート

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