Hydrochloric Acid → 2,2-Dimethyl-11-isopropyl-11-amino-undeca-4,8-dienal phenylhydrazone

HRID 1980024ノート

反応式

HRID 1980024 の反応式
[CH3:1][C:2]1([CH3:17])[CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([CH:14]([CH3:16])[CH3:15])[N:4]=[CH:3]1.Cl.[C:19]1([NH:25][NH2:26])[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1>O>[C:19]1([NH:25][N:26]=[CH:1][C:2]([CH3:3])([CH3:17])[CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([CH:14]([CH3:15])[CH3:16])[NH2:4])[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1

参加物

5

反応物 3

HCID 313Hydrochloric AcidHCID 7516PhenylhydrazineHCID 5575123,3-Dimethyl-12-isopropyl-1-aza-1,5,9-cyclododecatriene

生成物 1

HCID 705063962,2-Dimethyl-11-isopropyl-11-amino-undeca-4,8-dienal phenylhydrazone収率 100%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

The procedure as described in Example 1(b) is followed but with the use of 23.3 g (0.1 mol) of 3,3-dimethyl-12-isopropyl-1-aza-1,5,9-cyclododecatriene, 20 g of 37% hydrochloric acid, 20 ml of water and 10.8 g (0.1 mol) of phenylhydrazine. On processing as described in Example 1(b), there is obtained 34.1 g (0.1 mol) of 2,2-dimethyl-11-isopropyl-11-amino-undeca-4,8-dienal-phenylhydrazone; yield 100% of theory.

出典と根拠

ORDレコード
ord-6c36c3d57f6d4a27ba1f64e9033e6f95
出典データセット
uspto-grants-1984_11
特許番号
US04484004

反応ノート

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