Tricaprylin → Octanoic Acid

反応式

[C:1]([OH:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH3:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][C:28]([O:30][CH2:31][CH:32]([O:44][C:45]([CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH3:53])=[O:46])[CH2:33][O:34][C:35]([CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH3:43])=[O:36])=[O:29]>>[C:1]([OH:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[C:1]([OH:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH3:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][C:28]([O:30][CH2:31][CH:32]([O:44][C:45]([CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH3:53])=[O:46])[CH2:33][O:34][C:35]([CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH3:43])=[O:36])=[O:29]

参加物

反応物 2

HCID 10850Tricaprylin

HCID 445639Oleic Acid

生成物 3

HCID 379Octanoic Acid

HCID 10850Tricaprylin

HCID 445639Oleic Acid

反応条件

温度: 40 °C

実験手順

230 g of oleic acid (trade name: EXTRA OS-85, produced by NOF Corporation) and 69 g of enzyme powder prepared by Production Example 1 were added to 2070 g of tricaprylin (trade name: Tricaprylin, produced by Sigma Aldrich Japan) in 5000 mL reaction flask. Then, the enzyme reaction was conducted to the mixture stirring with propellers at 40° C. for 13 hours. The surviving enzymes were removed by filtration to obtain 2250 g of the reaction substance. After the reaction, each octanoic acid, oleic acid and tricaprylin was taken out from the reaction substance with a centrifugal molecular distillation equipment (produced by NIPPON SHARYO, LTD.) to obtain 270 g of a triglyceride containing substance.