Hydrochloric Acid → Myristyl chloride

HRID 1994377ノート

反応式

HRID 1994377 の反応式
[CH2:1](O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[ClH:16]>O>[CH2:1]([Cl:16])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]

参加物

4

反応物 2

HCID 313Hydrochloric AcidHCID 82091-Tetradecanol

生成物 1

HCID 17043Myristyl chloride

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

A 1 l jacketed glass reactor with a glass paddle stirrer, an immersed tube for reactant metering and an attached water separator is initially charged with 200 g of N-n-octylalkylpyridinium chloride (prepared according to Example 2) as catalyst and adjusted to a temperature of 150° C. 243 g of n-tetradecanol are introduced uniformly via the immersed tube within 4.5 h. Over the entire reaction time, gaseous hydrogen chloride in a slight excess is metered in via the immersed tube, while the water of reaction formed is removed distillatively from the reaction mixture. The performance of the reaction and workup are analogous to Example 4a. After a total reaction time of 7.5 h, the conversion based on n-tetradecanol is 99.5%.

後処理

  1. customadjusted to a temperature of 150° C
  2. customformed
  3. customis removed distillatively from the reaction mixture
  4. customThe performance of the reaction and workup
  5. customAfter a total reaction time of 7.5 h

出典と根拠

ORDレコード
ord-ba5422b6b1d14df6b23f24a769c8cdb4
出典データセット
uspto-grants-2010_01
特許番号
US07652180B2

反応ノート

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