Hydrochloric Acid → 1-Chlorooctadecane

HRID 1994378

反応式

HRID 1994378 の反応式
[CH2:1](O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[ClH:20]>O>[CH2:1]([Cl:20])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

参加物

4

反応物 2

HCID 313Hydrochloric AcidHCID 8221Stearyl Alcohol

生成物 1

HCID 188151-Chlorooctadecane

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

A 1 l jacketed glass reactor with a glass paddle stirrer and immersed tube for reactant metering is initially charged with 220 g of N-n-octylalkylpyridinium chloride (prepared according to Example 2) and adjusted to a temperature of 150° C. 447 g of n-octadecanol are introduced uniformly via an immersed tube over 5 hours. Gaseous hydrogen chloride is metered in via an immersed tube in a slight stoichiometric excess over the entire reaction time, and the water of reaction formed is simultaneously removed via distillation. The performance of the reaction and the workup of the reaction mixture are analogous to Example 4a. After a total reaction time of 8 h (including 3 hours of postreaction), the conversion based on n-octadecanol is 99.8%.

後処理

  1. customadjusted to a temperature of 150° C
  2. customformed
  3. customis simultaneously removed via distillation
  4. customThe performance of the reaction
  5. customAfter a total reaction time of 8 h (including 3 hours of postreaction)

出典と根拠

ORDレコード
ord-7bee728fb57641758eace0626d58fba8
出典データセット
uspto-grants-2010_01
特許番号
US07652180B2

関連ノート

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