{4-[(Undecyloxy)methyl]phenyl}methanol → 4-[(Undecyloxy)methyl]benzaldehyde
反応式
[CH2:1]([O:12][CH2:13][C:14]1[CH:21]=[CH:20][C:17]([CH2:18][OH:19])=[CH:16][CH:15]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[Cr](Cl)([O-])(=O)=O.[NH+]1C=CC=CC=1>C(Cl)Cl>[CH2:1]([O:12][CH2:13][C:14]1[CH:15]=[CH:16][C:17]([CH:18]=[O:19])=[CH:20][CH:21]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]参加物
4
実験手順
p-(n-Undecyloxymethyl)benzyl alcohol (10 mmoles) is dissolved in methylene chloride and treated with pyridinium chlorochromate (12 mmoles) at room temperature. When the reaction ceases, the reaction mixture is filtered through a pad of silica gel. The solvent is evaporated from this filtrate to afford the product, p-(n-undecyloxymethyl)benzaldehyde.