N-Hydroxy-3-trimethylsilyl-prop-2-ynimidoyl chloride → N-hydroxy-3-(m-tolyl)prop-2-ynimidoyl chloride

HRID 2040889ノート

反応式

HRID 2040889 の反応式
[OH:1][N:2]=[C:3]([Cl:10])[C:4]#[C:5][Si](C)(C)C.ON=CC#[C:15][C:16]1[CH:21]=[CH:20][CH:19]=[C:18](C)[CH:17]=1>>[OH:1][N:2]=[C:3]([Cl:10])[C:4]#[C:5][C:18]1[CH:17]=[C:16]([CH3:15])[CH:21]=[CH:20][CH:19]=1

参加物

3

反応物 2

HCID 86662874N-Hydroxy-3-trimethylsilyl-prop-2-ynimidoyl chlorideHCID 86662876N-hydroxy-3-(3-methylphenyl)prop-2-yn-1-imine

生成物 1

HCID 86662877N-hydroxy-3-(m-tolyl)prop-2-ynimidoyl chloride収率 96.4%

実験手順

The title compound was prepared following the method herein described for Compound 3b, using Compound 91c instead of 3-trimethylsilylprop-2-ynal oxime. The residue was used in the next step without further purification. Yield: 96.4%.

後処理

  1. customThe residue was used in the next step without further purification

出典と根拠

ORDレコード
ord-9aba6ff3f2f147f7b09a5ba1475bd47a
出典データセット
uspto-grants-2013_11
特許番号
US08580962B2

反応ノート

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