Hydrochloric Acid → Tris(dimethylaminomethyl)phosphine trihydrochloride
反応式
[CH3:1][N:2]([CH2:4][P:5]([CH2:10][N:11]([CH3:13])[CH3:12])[CH2:6][N:7]([CH3:9])[CH3:8])[CH3:3].[ClH:14]>C(O)C>[ClH:14].[ClH:14].[ClH:14].[CH3:3][N:2]([CH2:4][P:5]([CH2:10][N:11]([CH3:13])[CH3:12])[CH2:6][N:7]([CH3:9])[CH3:8])[CH3:1]参加物
4
実験手順
A rubber-capped serum bottle containing 25 ml of ethanol was purged of air with argon, and then charged by means of a syringe with 2.31 g (11.25 mmol) of tris(dimethylaminomethyl)phosphine and 7.00 ml (42.0 mmol) of 6N hydrochloric acid. The solution, which fumed but remained clear, was shaken for 30 min and then stripped under vacuum, leaving 3.55 g (100% yield) of tris(dimethylaminomethyl)phosphine trihydrochloride as a white, crystalline solid.
後処理
- customwas purged of air with argon
出典と根拠
- ORDレコード
- ord-b85e35f3dc4c4d189446de7c5d628789
- 出典データセット
- uspto-grants-1980_04
- 特許番号
- US04196149
反応ノート
読み込み中…