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(Bromodichloromethyl)phenylmercury → HCID 20344549、化合物
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | (Bromodichloromethyl)phenylmercury | HCID 76800 | — |
| 反応物 | Methyl 3-(4-chlorophenoxy)prop-2-enoate | HCID 53663470 | — |
| 溶媒 | Benzene | HCID 241 | — |
| 生成物 | HCID 20344549 | HCID 20344549 | — |
反応手順
A mixture of methyl 3-(4-chlorophenoxy)-2-propenoate (30 mmol), phenyl(bromodichloromethyl)mercury (30 mmol) and 50 ml benzene are heated under reflux, with stirring, for 4 hr, followed by TLC of the product. The mixture is then filtered and the solvent removed, giving methyl 3-(4-chlorophenoxy)-2,2-dichlorocyclopropanecarboxylate, which is then hydrolyzed and reacted with m-phenoxybenzyl bromide to give m-phenoxybenzyl 3-(4-chlorophenoxy)-2,2-dichlorocyclopropanecarboxylate.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04198527 |
| 出典データセット | uspto-grants-1980_04 |
| ORD ID | ord-08344fd5ddcf45489bc6732e73bd2fc0 |
| 出典メモ | uspto-grants-1980_04 |