1-Butanol → Butyl oxoacetate

HRID 2053500ノート

反応式

HRID 2053500 の反応式
[CH2:1]([OH:5])[CH2:2][CH2:3][CH3:4].[CH:6]([CH:8]=[O:9])=[O:7]>C(O)CCCCCCC>[C:8]([O:5][CH2:1][CH2:2][CH2:3][CH2:4][CH2:1][CH2:2][CH2:3][CH3:4])(=[O:9])[CH:6]=[O:7].[C:8]([O:5][CH2:1][CH2:2][CH2:3][CH3:4])(=[O:9])[CH:6]=[O:7]

参加物

5

反応物 2

HCID 2631-ButanolHCID 7860Glyoxal2 回

生成物 2

HCID 80521Butyl oxoacetateHCID 19834511Octyl oxoacetate

試薬・触媒・溶媒 1

HCID 9571-Octanol溶媒

実験手順

5.17 g of the butanol solution of glyoxal obtained in Example 2-11, 9.62 g of 1-octanol, and 0.6 g of the above-mentioned metal-loading carrier were put into an autoclave, and an oxidation reaction was conducted by the same operation as in Example 2-11. The reaction solution thus obtained was analyzed, which revealed the glyoxal conversion to be 90%, and the combined 1-octyl glyoxylate and 1-butyl glyoxylate (the product) selectivity and yield to be 74% and 67%, respectively.

後処理

  1. customan oxidation reaction
  2. customThe reaction solution thus obtained

出典と根拠

ORDレコード
ord-3b39c16de8b145658d7beb85bca752c7
出典データセット
uspto-grants-2008_02
特許番号
US07326806B2

反応ノート

読み込み中…