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Safrole → Safrole oxide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Safrole | HCID 5144 | — |
| 反応物 | Perpropionic acid | HCID 65136 | — |
| 溶媒 | 1,1-Dichloropropane | HCID 6573 | — |
| 生成物 | Safrole oxide | HCID 101123 | — |
反応手順
48.82 g (0.3 mol) of 5-(2-propenyl)-1,3-benzodioxole were reacted with 45 g (0.1 mol) of a 20% strength solution of perpropionic acid in dichloropropane at 30° C. as described in Example 1. After a reaction time of 6 hours, the peracid conversion was 96%. 5-(Oxiranylmethyl)-1,3-benzodioxole was formed with a selectivity of 68%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04212809 |
| 出典データセット | uspto-grants-1980_07 |
| ORD ID | ord-0e6bb625f7d6498f99187530cf82f287 |
| 出典メモ | uspto-grants-1980_07 |