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Benzylammonium chloride → 3-Benzylaminoacrylonitrile
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzylammonium chloride | HCID 2724127 | — |
| 反応物 | Sodium 3-hydroxyacrylonitrile | HCID 86738287 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | 3-Benzylaminoacrylonitrile | HCID 70548701 | 57.1% |
反応手順
32.5 g (0.25 mol) of sodium-3-hydroxyacrylonitrile (content 70%) and 43.1 g (0.3 mol) of benzylamine hydrochloride are refluxed for 5 h in 150 ml of acetonitrile. After removal of the solid by filtration and withdrawal of the solvent, the product was dissolved in chloroform and washed with water. Subsequent vacuum distillation yielded 22.6 g of 3-benzylaminoacrylonitrile (57.1%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04319024 |
| 出典データセット | uspto-grants-1982_03 |
| ORD ID | ord-0f57112ce6d9455cb4c8af2ad9496e10 |
| 出典メモ | uspto-grants-1982_03 |