Potassium tert-butoxide → HCID 13702609、化合物
反応式
C(=[C:5]1[C:10]([CH2:11][NH2:12])=[CH:9][CH:8]=[CH:7][NH:6]1)C(C)C.[CH3:13][C:14]([O-])([CH3:16])[CH3:15].[K+]>C1(C)C=CC=CC=1>[N:6]1[CH:7]=[CH:8][CH:9]=[C:10]([CH:11]=[N:12][CH2:13][CH:14]([CH3:16])[CH3:15])[CH:5]=1参加物
4
実験手順
The procedure is carried out as in Example 1 (b) but with the use of 80.1 g (0.495 mol) of isobutylidene-3-aminomethylpyridine, 2.5 g (0.0223 mol) of potassium tert-butylate and 75 ml of toluene. After a reaction time of 1 hour at 30°-35° C., distillation yields 74.5 g (0.46 mol) of 3-pyridylmethylidene-isobutylamine; yield 93% of theory; b.p. 108° C./2×103Pa; nD20 =1.5198.
後処理
- distillationAfter a reaction time of 1 hour at 30°-35° C., distillation
出典と根拠
- ORDレコード
- ord-256c67fb114d46ca956cfe3d7e536726
- 出典データセット
- uspto-grants-1982_03
- 特許番号
- US04322536
反応ノート
読み込み中…