HCID 11263568、化合物 → HCID 178502706、化合物

HRID 2059484ノート

反応式

HRID 2059484 の反応式
CON(C)C(=O)CC(=O)O.Cc1ccc(C)c(OCCCC(C)(C)C=O)c1>C1CCNCC1.CN(C)c1ccncc1.Cc1ccccc1>CON(C)C(=O)/C=C/C(C)(C)CCCOc1cc(C)ccc1C

参加物

6

反応物 2

HCID 11263568HCID 11263568、化合物HCID 222208795-(2,5-Dimethylphenoxy)-2,2-dimethylpentanal

生成物 1

HCID 178502706HCID 178502706、化合物収率 0%

試薬・触媒・溶媒 3

HCID 142844-(Dimethylamino)pyridine試薬HCID 8082Piperidine触媒HCID 1140Toluene溶媒

反応条件

温度
25 °C

後処理

  1. temperatureThe product mixture was cooled to 25 °C.
  2. filtrationFiltered through a pad of celite · Organic 相を保持
  3. wash"The celite was washed with ethyl acetate (3 x 1 mL)."
  4. concentrationThe filtrate was concentrated under reduced pressure
  5. additionA 0.07 M stock solution of the internal standard ethylene carbonate (0.70 mL in CDCl3) was added.

出典と根拠

ORDレコード
ord-4e8221d59f8f42f8814175932982c123
出典データセット
Transfer learning optimization of 26 decarboxylative olefination reactions

反応ノート

読み込み中…