Allyl acetate → Tetraethylsilane

HRID 20616

反応式

HRID 20616 の反応式
F[B-](F)(F)F.C(OCC=C)(=O)C.C([SiH](CC)CC)C.[CH2:20]([Si:23]([CH2:28][CH3:29])([CH2:26][CH3:27])[CH2:24][CH3:25])[CH:21]=C>C1(C)C=CC=CC=1>[CH2:20]([Si:23]([CH2:28][CH3:29])([CH2:26][CH3:27])[CH2:24][CH3:25])[CH3:21]

参加物

6

反応物 4

HCID 11584Allyl acetateHCID 12052TriethylsilaneHCID 26255TetrafluoroborateHCID 11194462Allyltriethylsilane

生成物 1

HCID 12426Tetraethylsilane収率 5%

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

In a reactor were placed bis(1,5-cyclooctadiene)iridium tetrafluoroborate [Ir(cod)2]+BF4− (0.05 mmol), allyl acetate (20 mmol), and toluene (3 ml). The mixture was raised in temperature to 80° C. in a nitrogen atmosphere, triethylsilane (Et3SiH)(5 mmol) was added thereto over one hour, and a reaction was conducted at 80° C. for one hour. After the reaction, the reaction mixture was analyzed by gas chromatography to find that allyltriethylsilane was produced in a yield of 54% and tetraethylsilane was by-produced in a yield of 5%.

後処理

  1. customIn a reactor were placed
  2. additionwas added
  3. waita reaction was conducted at 80° C. for one hour
  4. customAfter the reaction
  5. customwas produced in a yield of 54%

出典と根拠

ORDレコード
ord-49ca4e2f681548ffad2587d89196df70
出典データセット
uspto-grants-2010_06
特許番号
US07745654B2

関連ノート

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