Allyl acetate → Tetraethylsilane
反応式
F[B-](F)(F)F.C(OCC=C)(=O)C.C([SiH](CC)CC)C.[CH2:20]([Si:23]([CH2:28][CH3:29])([CH2:26][CH3:27])[CH2:24][CH3:25])[CH:21]=C>C1(C)C=CC=CC=1>[CH2:20]([Si:23]([CH2:28][CH3:29])([CH2:26][CH3:27])[CH2:24][CH3:25])[CH3:21]参加物
6
実験手順
In a reactor were placed bis(1,5-cyclooctadiene)iridium tetrafluoroborate [Ir(cod)2]+BF4− (0.05 mmol), allyl acetate (20 mmol), and toluene (3 ml). The mixture was raised in temperature to 80° C. in a nitrogen atmosphere, triethylsilane (Et3SiH)(5 mmol) was added thereto over one hour, and a reaction was conducted at 80° C. for one hour. After the reaction, the reaction mixture was analyzed by gas chromatography to find that allyltriethylsilane was produced in a yield of 54% and tetraethylsilane was by-produced in a yield of 5%.
後処理
- customIn a reactor were placed
- additionwas added
- waita reaction was conducted at 80° C. for one hour
- customAfter the reaction
- customwas produced in a yield of 54%
出典と根拠
- ORDレコード
- ord-49ca4e2f681548ffad2587d89196df70
- 出典データセット
- uspto-grants-2010_06
- 特許番号
- US07745654B2
反応ノート
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