Cesium carbonate → 2-Bromo-6-{6-[2-(2-hydroxy-ethoxy)-1,1-dimethyl-ethyl]-1-oxo-3,4-dihydro-1H-isoquinolin-2-yl}-benzaldehyde

反応式

[OH:1][CH2:2][C:3]([C:6]1[CH:7]=[C:8]2[C:13](=[CH:14][CH:15]=1)[C:12](=[O:16])[N:11](CC1C=CC(OC)=CC=1)[CH2:10][CH2:9]2)([CH3:5])[CH3:4].Br[C:27]1[CH:34]=[CH:33][CH:32]=[C:31]([Br:35])[C:28]=1[CH:29]=[O:30].C(=O)([O-])[O-].[Cs+].[Cs+].[O:42]1CCO[CH2:44][CH2:43]1>C1C=CC(/C=C/C(/C=C/C2C=CC=CC=2)=O)=CC=1.C1C=CC(/C=C/C(/C=C/C2C=CC=CC=2)=O)=CC=1.[Pd].CC1(C)C2C(=C(P(C3C=CC=CC=3)C3C=CC=CC=3)C=CC=2)OC2C(P(C3C=CC=CC=3)C3C=CC=CC=3)=CC=CC1=2>[Br:35][C:31]1[CH:32]=[CH:33][CH:34]=[C:27]([N:11]2[CH2:10][CH2:9][C:8]3[C:13](=[CH:14][CH:15]=[C:6]([C:3]([CH3:4])([CH3:5])[CH2:2][O:1][CH2:44][CH2:43][OH:42])[CH:7]=3)[C:12]2=[O:16])[C:28]=1[CH:29]=[O:30]