Allyl chloride → 2-Bromo-1-chloropropane
反応式
[Br:1][CH2:2][CH2:3][CH2:4][Cl:5].[CH2:6]([Cl:9])[CH:7]=[CH2:8]>C1CCCCC1>[Br:1][CH2:2][CH2:3][CH2:4][Cl:5].[Br:1][CH:7]([CH3:8])[CH2:6][Cl:9]参加物
5
実験手順
The same process as in example 2 was carried out, but the cyclohexane was replaced by 3-bromo-1-chloropropane. The reaction developed in the same way. After 30 minutes of irradiation at 22° C, 90% of allyl chloride had been converted. The reaction product was degassed and the unreacted allyl chloride was distilled. The remaining product was formed by 3-bromo-1-chloropropane (solvent + formed product) and about 3% of 2-bromo-1-chloropropane. This operation has the advantage of making the solvent distillation unnecessary.
後処理
- customAfter 30 minutes of irradiation at 22° C
- customThe reaction product was degassed
- distillationthe unreacted allyl chloride was distilled
出典と根拠
- ORDレコード
- ord-fd729aa701f2427aaa34fce67080442c
- 出典データセット
- uspto-grants-1977_09
- 特許番号
- US04049516
反応ノート
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