関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 1,2-Dichlorobenzene | HCID 7239 | — |
| 反応物 | 1,1,2,3,3,3-Hexachloro-1-propene | HCID 15902 | — |
| 反応物 | Tetrachloroethylene | HCID 31373 | — |
| 生成物 | Hexachloroindene | HCID 53971155 | 48.7% |
反応手順
A mixture containing 29.4 grams (0.2 mole), of ortho-dichlorobenzene, 50 grams (0.2 moles) of hexachloropropylene and 2.5 grams of ferric chloride in 250 milliliters of perchloroethylene was heated and stirred by the process of Example I for about 4 hours at reflux (125° C.). The reaction mixture was then washed with concentrated hydrochloric acid, then water and distilled to give a 48.7% yield of hexachloroindene. The product was confirmed by infrared and NMR spectra analysis as structured.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04049727 |
|---|
| 出典データセット | uspto-grants-1977_09 |
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| ORD ID | ord-ebe79f31ccfc476ca69a935b53df9376 |
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| 出典メモ | uspto-grants-1977_09 |
|---|
