化工社化工社 化学情報印刷レポート · 研究参考用
m-Chloroperbenzoic acid → Pyridine, 2-[[(2-methylphenyl)methyl]sulfinyl]-, 1-oxide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 反応物 | 2-(2-methylphenylmethylthio)pyridine N-oxide | HCID 45692352 | — |
| 溶媒 | Chloroform | HCID 6212 | — |
| 生成物 | Pyridine, 2-[[(2-methylphenyl)methyl]sulfinyl]-, 1-oxide | HCID 501068 | — |
反応手順
To a vigorously stirred solution of 6.9 gm (0.03 mol) of 2-(2-methylphenylmethylthio)pyridine N-oxide in 50 ml of chloroform maintained at 0° to 10° C. is slowly added a solution of 6 gm (0.03 mol) MCPBA (85%) in 100 ml of chloroform. When addition is complete the temperature is allowed to rise to ambient. After sixteen hours the reaction solution is washed up in the manner described in Example 139.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04050921 |
| 出典データセット | uspto-grants-1977_09 |
| ORD ID | ord-e8ec416a33d04210a65bab9cac42d512 |
| 出典メモ | uspto-grants-1977_09 |