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m-Chloroperbenzoic acid → 4-(4-(2-Quinolinylmethylsulfinyl)styryl)benzoic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 反応物 | Potassium Bicarbonate | HCID 516893 | — |
| 反応物 | 4-(4-(2-Quinolinylmethylthio)styryl)benzoic acid | HCID 54156044 | — |
| 溶媒 | 1,2-Dichloroethylene | HCID 10900 | — |
| 生成物 | 4-(4-(2-Quinolinylmethylsulfinyl)styryl)benzoic acid | HCID 54512756 | — |
反応手順
4-(4-(2-quinolinylmethylthio)styryl)benzoic acid (4 mmol) in dichloroethene (50 ml) is stirred with m-chloroperbenzoic acid (4 mmol) and solid potassium hydrogen carbonate (1.0 g). The reaction is assayed by TLC and upon consumption of the starting thio compound, the mixture is filtered, washed with dilute aqueous sodium bisulfite, dried and evaporated to give 4-(4-(2-quinolinylmethylsulfinyl)styryl)benzoic acid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04920130 |
| 出典データセット | uspto-grants-1990_04 |
| ORD ID | ord-31119d159f3d4c278c7e282373e48453 |
| 出典メモ | uspto-grants-1990_04 |