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2-(5-Oxiranyl-furan-2-yl)-[1,3]dioxolane → (5-[1,3]Dioxolan-2-yl-furan-2-yl)-acetaldehyde
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-(5-Oxiranyl-furan-2-yl)-[1,3]dioxolane | HCID 23130765 | — |
| 溶媒 | Ethyl Acetate | HCID 8857 | — |
| 生成物 | (5-[1,3]Dioxolan-2-yl-furan-2-yl)-acetaldehyde | HCID 86042298 | 69.8% |
反応手順
The resulting 2-(5-oxiranyl-furan-2-yl)-[1,3]dioxolane (2.25 g) and silica gel (5.00 g) were suspended in ethyl acetate (40 mL), and the solution was stirred for 6.5 hours at room temperature. The reaction solution was filtered, then, the filtrate was evaporated in vacuo, and (5-[1,3]dioxolan-2-yl-furan-2-yl)-acetaldehyde (1.57 g) was obtained as a yellow oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07932272B2 |
| 出典データセット | uspto-grants-2011_04 |
| ORD ID | ord-e5c89323eebe410eaa5f3bbf613666b1 |
| 出典メモ | uspto-grants-2011_04 |