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HRID 2080112作成日:2026年10月27日

2-(5-Oxiranyl-furan-2-yl)-[1,3]dioxolane → (5-[1,3]Dioxolan-2-yl-furan-2-yl)-acetaldehyde

https://huagongshe.com/reaction/2080112

反応式

関与物質

役割名称HCID仕込み量
反応物2-(5-Oxiranyl-furan-2-yl)-[1,3]dioxolaneHCID 23130765—
溶媒Ethyl AcetateHCID 8857—
生成物(5-[1,3]Dioxolan-2-yl-furan-2-yl)-acetaldehydeHCID 8604229869.8%

反応手順

The resulting 2-(5-oxiranyl-furan-2-yl)-[1,3]dioxolane (2.25 g) and silica gel (5.00 g) were suspended in ethyl acetate (40 mL), and the solution was stirred for 6.5 hours at room temperature. The reaction solution was filtered, then, the filtrate was evaporated in vacuo, and (5-[1,3]dioxolan-2-yl-furan-2-yl)-acetaldehyde (1.57 g) was obtained as a yellow oil.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US07932272B2
出典データセットuspto-grants-2011_04
ORD IDord-e5c89323eebe410eaa5f3bbf613666b1
出典メモuspto-grants-2011_04