2-Octanol, 1,1,1-trifluoro- → 4-(1,1,1-Trifluoro-2-octyloxycarbonyl)phenyl 4'-n-undecylbiphenyl-4-carboxylate

HRID 2081526

反応式

HRID 2081526 の反応式
[F:1][C:2]([F:12])([F:11])[CH:3]([OH:10])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].C(C1C=CC([C:28]2[CH:33]=[CH:32][C:31]([C:34](O)=[O:35])=[CH:30][CH:29]=2)=CC=1)CCCCCCCC.C(C1C=CC(C2C=CC(C(O)=O)=CC=2)=CC=1)CCCCCCCCC.[CH2:62]([C:73]1[CH:78]=[CH:77][C:76]([C:79]2[CH:84]=[CH:83][C:82]([C:85]([OH:87])=[O:86])=[CH:81][CH:80]=2)=[CH:75][CH:74]=1)[CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68][CH2:69][CH2:70][CH2:71][CH3:72].C(OC1C=C(C(O)=O)C(C2C=CC=CC=2)=CC=1)CCCCCCCCC>>[CH2:62]([C:73]1[CH:74]=[CH:75][C:76]([C:79]2[CH:84]=[CH:83][C:82]([C:85]([O:87][C:28]3[CH:33]=[CH:32][C:31]([C:34]([O:10][CH:3]([CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9])[C:2]([F:11])([F:12])[F:1])=[O:35])=[CH:30][CH:29]=3)=[O:86])=[CH:81][CH:80]=2)=[CH:77][CH:78]=1)[CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68][CH2:69][CH2:70][CH2:71][CH3:72]

参加物

6

反応物 5

HCID 978042-Octanol, 1,1,1-trifluoro-HCID 17293304-(4-Undecylphenyl)benzoic acidHCID 30921384'-Nonyl-biphenyl-4-carboxylic acidHCID 114050114'-n-Decyl-4-carboxybiphenylHCID 212523924-n-Decyloxybiphenylcarboxylic acid

生成物 1

HCID 544613024-(1,1,1-Trifluoro-2-octyloxycarbonyl)phenyl 4'-n-undecylbiphenyl-4-carboxylate

実験手順

Example 1s were repeated except that optically active 1,1,1-trifluoro-2-octanol was used in place of the 1,1,1-trifluoro-2-decanol used in example 1,1, and 4'-n-nonylbiphenyl-4-carboxylic acid, 4'-n-decylbiphenyl-4-carboxylic acid and 4'-n-undecylbiphenyl-4-carboxylic acid were used in place of the 4-n-decyloxybiphenylcarboxylic acid to obtain the titled compounds, respectively.

出典と根拠

ORDレコード
ord-2fbf7bc6990f47968122203d1e4a45dd
出典データセット
uspto-grants-1993_02
特許番号
US05184847

関連ノート

読み込み中…