1-Amino-2-propanol → HCID 19778845、化合物

HRID 2081901ノート

反応式

HRID 2081901 の反応式
[N+:1]([C:4]1[CH:9]=[C:8]([CH3:10])[CH:7]=[C:6]([N+:11]([O-:13])=[O:12])[C:5]=1OC)([O-:3])=[O:2].[NH2:16][CH2:17][CH:18]([OH:20])[CH3:19]>O>[N+:1]([C:4]1[CH:9]=[C:8]([CH3:10])[CH:7]=[C:6]([N+:11]([O-:13])=[O:12])[C:5]=1[NH:16][CH2:17][CH:18]([OH:20])[CH3:19])([O-:3])=[O:2]

参加物

4

反応物 2

HCID 41-Amino-2-propanolHCID 2596494-Methoxy-3,5-dinitrotoluene

生成物 1

HCID 19778845HCID 19778845、化合物

試薬・触媒・溶媒 1

HCID 962Water溶媒

反応条件

温度
60 °C

実験手順

0.05 mol (10.6 g) of 2,6-dinitro-4-methylanisole is introduced gradually, whilst stirring, into 30 ml of 1-aminopropan-2-ol. The reaction medium is heated at 60° C. for 30 minutes and then poured into 120 g of iced water. The expected product precipitates. It is filtered off, washed with water and then recrystallised from an aqueous-alcoholic mixture. After drying in vacuo, it melts at 80° C.

後処理

  1. customThe expected product precipitates
  2. filtrationIt is filtered off
  3. washwashed with water
  4. customrecrystallised from an aqueous-alcoholic mixture
  5. customAfter drying in vacuo, it melts at 80° C.

出典と根拠

ORDレコード
ord-b0181f307cc044048f50eadd6ebfbbe6
出典データセット
uspto-grants-1993_02
特許番号
US05186717

反応ノート

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