Acetic Acid → Acetic acid--1-ethyl-1H-imidazole (1/1)
反応式
[C:1]([OH:4])(=[O:3])[CH3:2].[CH2:5]([N:7]1[CH:11]=[CH:10][N:9]=[CH:8]1)[CH3:6]>C(OCC)C>[C:1]([O-:4])(=[O:3])[CH3:2].[CH2:5]([N+:7]1[CH:11]=[CH:10][NH:9][CH:8]=1)[CH3:6]参加物
4
実験手順
First, 6 ml of 99.7% acetic acid was added to 10 g of N-ethylimidazole, and the resultant mixture was stirred for 12 hours at a temperature kept at 0° C. The resultant reaction product was added dropwise to 1000 ml of diethyl ether under stirring. The diethyl ether was distilled off at room temperature, and the residue was dried under vacuum to precipitate crystals. The precipitated crystals were recovered to obtain 15.9 g of N-ethylimidazolium acetate. The product had a glass transition temperature of −51.7° C.
後処理
- customkept at 0° C
- customThe resultant reaction product
- distillationThe diethyl ether was distilled off at room temperature
- customthe residue was dried under vacuum
- customto precipitate crystals
- customThe precipitated crystals were recovered
出典と根拠
- ORDレコード
- ord-26d8ff0da90a404e984d0ed38eb8c1ef
- 出典データセット
- uspto-grants-2010_06
- 特許番号
- US07746623B2
反応ノート
読み込み中…