Ethyl 2-acetoxy-5-benzylideneaminobenzoate → Ethyl 2-acetoxy-5-aminobenzoate
反応式
[C:1]([O:4][C:5]1[CH:15]=[CH:14][C:13]([N:16]=CC2C=CC=CC=2)=[CH:12][C:6]=1[C:7]([O:9][CH2:10][CH3:11])=[O:8])(=[O:3])[CH3:2]>O.C(O)C>[C:1]([O:4][C:5]1[CH:15]=[CH:14][C:13]([NH2:16])=[CH:12][C:6]=1[C:7]([O:9][CH2:10][CH3:11])=[O:8])(=[O:3])[CH3:2]参加物
3
実験手順
Ethyl 2-acetoxy-5-benzylideneaminobenzoate (10.0 g, 32.2 mmole) was refluxed in water-ethanol (3:1, 750 ml) for about 1 hour, after which time the mixture was cooled and the precipitate isolated by filtration. After a further recrystallization this gave the title compound (3.0 g, 42%), m.p. 82.5°-83° C. Found (Calc. for C11H13NO4) C 58.96 (59.19). H 5.98 (5.83), N 6.22 (6.28).
後処理
- temperatureafter which time the mixture was cooled
- customthe precipitate isolated by filtration
- customAfter a further recrystallization
出典と根拠
- ORDレコード
- ord-c69dbda3f6724b44b4af56b86265de17
- 出典データセット
- uspto-grants-1990_06
- 特許番号
- US04933330
反応ノート
読み込み中…