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Water → Oxirane, 2-((4-chlorophenyl)methyl)-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 反応物 | 1-Allyl-4-chlorobenzene | HCID 11019064 | — |
| 溶媒 | Chloroform | HCID 6212 | — |
| 生成物 | Oxirane, 2-((4-chlorophenyl)methyl)- | HCID 148012 | — |
反応手順
To a solution of 3-(4-chlorophenyl)prop-1-ene (9.0 g) in chloroform (100 ml) was added portionwise metachloroperbenzoic acid (12.2 g), and the solution was stirred for 5 h at room temperature. The mixture was poured into water, the water layer was separated and the organic layer washed successively with sodium bicaronate, sodium sulphite and water. After drying, evaporation of the solvent gave 1-(4-chlorophenyl)-2,3-epoxypropane as a pale yellow oil. (9.51 g). NMR in CDCl3 :
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04933357 |
| 出典データセット | uspto-grants-1990_06 |
| ORD ID | ord-b212209cb977459caa6ffe79f2a61af2 |
| 出典メモ | uspto-grants-1990_06 |