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HRID 2107064作成日:2026年10月26日

Water → Oxirane, 2-((4-chlorophenyl)methyl)-

https://huagongshe.com/reaction/2107064

反応式

関与物質

役割名称HCID仕込み量
反応物WaterHCID 962—
反応物m-Chloroperbenzoic acidHCID 70297—
反応物1-Allyl-4-chlorobenzeneHCID 11019064—
溶媒ChloroformHCID 6212—
生成物Oxirane, 2-((4-chlorophenyl)methyl)-HCID 148012—

反応手順

To a solution of 3-(4-chlorophenyl)prop-1-ene (9.0 g) in chloroform (100 ml) was added portionwise metachloroperbenzoic acid (12.2 g), and the solution was stirred for 5 h at room temperature. The mixture was poured into water, the water layer was separated and the organic layer washed successively with sodium bicaronate, sodium sulphite and water. After drying, evaporation of the solvent gave 1-(4-chlorophenyl)-2,3-epoxypropane as a pale yellow oil. (9.51 g). NMR in CDCl3 :

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US04933357
出典データセットuspto-grants-1990_06
ORD IDord-b212209cb977459caa6ffe79f2a61af2
出典メモuspto-grants-1990_06