Aniline → 4-(2-Methyl-4-pyridinyloxy)aniline
反応式
[CH2:1]([O:5][C:6]1[CH:11]=[CH:10][C:9](SC2C=CC(N)=CC=2)=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].C(OC1C=CC(SC2C=C[C:35]([N+:38]([O-])=O)=[CH:34]C=2)=CC=1)CCC.[NH2:41]C1C=CC=CC=1.FC(F)(F)C1C=C(C=CC=1SC1C=CN=CC=1)N>CCOC(C)=O>[CH3:4][C:3]1[CH:2]=[C:1]([O:5][C:6]2[CH:7]=[CH:8][C:9]([NH2:41])=[CH:10][CH:11]=2)[CH:34]=[CH:35][N:38]=1参加物
6
実験手順
4-(4-Butoxyphenyl)thioaniline: 4-(4-Butoxyphenyl)thio-1-nitrobenzene was reduced to the aniline in a manner analagous to that used in the preparation of 3-(trifluoromethyl)-4-(4-pyridinylthio)aniline (Method B3b, Step 2): TLC (33% EtOAc/77% hexane) Rf 0.38. A16. General Method for Synthesis of Substituted Anilines by the Acylation of Diaminoarenes
出典と根拠
- ORDレコード
- ord-5dacecc7768b447187dd34983cce4998
- 出典データセット
- uspto-grants-2009_04
- 特許番号
- US07517880B2
反応ノート
読み込み中…