Pivalic acid → copper(II) pivalate
反応式
C([O-])([O-])=O.O.O.[Cu:7].[Cu+2].[C:9]([OH:15])(=[O:14])[C:10]([CH3:13])([CH3:12])[CH3:11]>O>[C:9]([O-:15])(=[O:14])[C:10]([CH3:13])([CH3:12])[CH3:11].[C:9]([O-:15])(=[O:14])[C:10]([CH3:13])([CH3:12])[CH3:11].[Cu+2:7]参加物
4
実験手順
To a suspension of 13.6 g of CuCO3.Cu(OH)2 in 50 ml of water is added, dropwise at rt, a solution of 18.6 g of pivalic acid in 100 ml of hot water, and the mixture is stirred until the evolution of gas has ceased. The reaction mixture is filtered by suction and the precipitate is washed four times with water. The precipitate is taken up in 300 ml of THF, the insoluble material is filtered off and the filtrate is concentrated under vacuum. 7.2 g of the expected product are obtained after drying under vacuum.
後処理
- additionis added, dropwise at rt
- filtrationThe reaction mixture is filtered by suction
- washthe precipitate is washed four times with water
- filtrationthe insoluble material is filtered off
- concentrationthe filtrate is concentrated under vacuum
出典と根拠
- ORDレコード
- ord-5e76fbf4cff947afac4386b2f7e10a4d
- 出典データセット
- uspto-grants-2009_04
- 特許番号
- US07521449B2
反応ノート
読み込み中…