2-Trans,6-trans,10-trans-geranylgeranyl diphosphate(3-) → syn-Copalyl diphosphate

反応式

[O:1]([CH2:10]/[CH:11]=[C:12](/[CH2:14][CH2:15]/[CH:16]=[C:17](\[CH3:29])/[CH2:18][CH2:19]/[CH:20]=[C:21](/[CH2:23][CH2:24][CH:25]=[C:26]([CH3:28])[CH3:27])\[CH3:22])\[CH3:13])[P:2]([O:5][P:6]([O-:9])([O-:8])=[O:7])(=[O:4])[O-:3].C/C(/CC[C@H]1[C@@]2(C)CCCC(C)(C)[C@H]2CCC1=C)=C\CO>>[CH3:13]/[C:12](/[CH2:14][CH2:15][C@H:16]1[C@@:21]2([CH3:22])[CH2:23][CH2:24][CH2:25][C:26]([CH3:28])([CH3:27])[C@@H:20]2[CH2:19][CH2:18][C:17]1=[CH2:29])=[CH:11]\[CH2:10][O:1][P:2]([O:5][P:6]([OH:9])([OH:8])=[O:7])([OH:3])=[O:4]

参加物

反応物 2

HCID 54971052-Trans,6-trans,10-trans-geranylgeranyl diphosphate(3-)

HCID 91697686Copalol

生成物 1

HCID 5281991syn-Copalyl diphosphate

実験手順

Chemicals. The preparation of (E,E,E)-geranylgeranyl diphosphate (GGPP), and ent- and syn-copalyl diphosphate (CPP), from the corresponding copalol stereoisomers (Yee and Coates 1992), has been previously described (Mohan et al. 1996). Unless otherwise noted, all other chemicals were purchased from Fisher Scientific (Fairlawn, N.J., USA).

出典と根拠

ORDレコード: ord-fc9042de1aa84f42b61ce73e68ff26cf
出典データセット: uspto-grants-2009_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07525016B1

反応ノート

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