Lithium bis((trifluoromethyl)sulfonyl)azanide → HCID 178483696、化合物

HRID 2116843

反応式

HRID 2116843 の反応式
[N-:1]([S:9]([C:12]([F:15])([F:14])[F:13])(=[O:11])=[O:10])[S:2]([C:5]([F:8])([F:7])[F:6])(=[O:4])=[O:3].[Li+].[CH3:17][N:18]([C:20]([N:23]([CH3:25])[CH3:24])(Cl)[Cl:21])[CH3:19]>O>[N-:1]([S:2]([C:5]([F:8])([F:6])[F:7])(=[O:4])=[O:3])[S:9]([C:12]([F:15])([F:14])[F:13])(=[O:11])=[O:10].[CH3:17][N:18]([C+:20]([N:23]([CH3:25])[CH3:24])[Cl:21])[CH3:19]

参加物

4

反応物 2

HCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanideHCID 125447451,1-Dichloro-N,N,N',N'-tetramethylmethanediamine

生成物 1

HCID 178483696HCID 178483696、化合物収率 85.2%

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

134.1 g (0.467 mol) of lithium bis(trifluoromethanesulfonyl)imide in 200 ml of water are added with stirring at room temperature to a solution of 80.0 g (0.468 mol) of bis(dimethylamino)dichloromethane in 300 ml of water. The mixture is stirred for half an hour, and the solid is subsequently filtered off. After repeated washing with 100 ml of water, the crystals formed are dried at 50° C. under a reduced pressure of 10.0 Pa, giving 165.5 g of bis(dimethylamino)chlorocarbenium bis(trifluoromethanesulfonyl)imide, corresponding to a yield of 85.1%.

後処理

  1. filtrationthe solid is subsequently filtered off
  2. washAfter repeated washing with 100 ml of water
  3. customthe crystals formed
  4. customare dried at 50° C. under a reduced pressure of 10.0 Pa

出典と根拠

ORDレコード
ord-61f7532d13544a869923ec3cb9b1a9db
出典データセット
uspto-grants-2008_10
特許番号
US07439395B2

関連ノート

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