化工社化工社 化学情報印刷レポート · 研究参考用
Hydrogen Peroxide → 3-(allylsulphinyl)-L-alanine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrogen Peroxide | HCID 784 | — |
| 反応物 | L-(+)-Cysteine | HCID 5862 | — |
| 反応物 | Allyl bromide | HCID 7841 | — |
| 生成物 | 3-(allylsulphinyl)-L-alanine | HCID 87310 | 15.7% |
反応手順
Alliin was synthesized from L-cysteine and allyl bromide following oxidation by H2O2 by the procedure of Stoll and Seebeck, 1951. The stereospecific product obtained, (+)S-allyl-L-cysteine sulfoxide (M.P.=164°, [α]D in H2O+62.1°), was identical to the natural substrate, alliin (Yield: 15.7%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06689588B1 |
| 出典データセット | uspto-grants-2004_02 |
| ORD ID | ord-cab322929182430ea80d8cd7f54e6635 |
| 出典メモ | uspto-grants-2004_02 |