Formic Acid → 3-Butyl-6-formamido-phthalide

HRID 2120180

反応式

HRID 2120180 の反応式
[NH2:1][C:2]1[CH:11]=[C:10]2[C:5]([CH:6]([CH2:12][CH2:13][CH2:14][CH3:15])[O:7][C:8]2=[O:9])=[CH:4][CH:3]=1.[CH:16](O)=[O:17]>>[CH2:12]([CH:6]1[C:5]2[C:10](=[CH:11][C:2]([NH:1][CH:16]=[O:17])=[CH:3][CH:4]=2)[C:8](=[O:9])[O:7]1)[CH2:13][CH2:14][CH3:15]

参加物

3

反応物 2

HCID 284Formic AcidHCID 98777066-Amino-3-butyl-phthalide

生成物 1

HCID 98345703-Butyl-6-formamido-phthalide

実験手順

A solution of 3.07 g (0.015 mol) of the compound obtained in Example 4 in 15 ml of 85% formic acid is heated to 60° C. An hour later the reaction mixture is poured into ice-water. The separated solid is collected and crystallised from dilute ethanol to give the title compound.

後処理

  1. customThe separated solid is collected
  2. customcrystallised from dilute ethanol

出典と根拠

ORDレコード
ord-3ff838d2a1064b6aa58b0000a78b057b
出典データセット
uspto-grants-2004_02
特許番号
US06689808B2

関連ノート

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