Triphenylsulfonium chloride → HCID 23435220、化合物
反応式
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([O:11][C:12]2[CH:13]=[C:14]3[C:19](=[CH:20][CH:21]=2)[CH:18]=[C:17]([S:22]([O-:25])(=[O:24])=[O:23])[CH:16]=[CH:15]3)(=[O:10])=[O:9])=[CH:4][CH:3]=1.[Na+].[Cl-].[C:28]1([S+:34]([C:41]2[CH:46]=[CH:45][CH:44]=[CH:43][CH:42]=2)[C:35]2[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=2)[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1>ClCCl>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([O:11][C:12]2[CH:13]=[C:14]3[C:19](=[CH:20][CH:21]=2)[CH:18]=[C:17]([S:22]([O-:25])(=[O:24])=[O:23])[CH:16]=[CH:15]3)(=[O:9])=[O:10])=[CH:4][CH:3]=1.[C:41]1([S+:34]([C:28]2[CH:29]=[CH:30][CH:31]=[CH:32][CH:33]=2)[C:35]2[CH:40]=[CH:39][CH:38]=[CH:37][CH:36]=2)[CH:42]=[CH:43][CH:44]=[CH:45][CH:46]=1参加物
4
実験手順
The sodium 6-(4′-methylphenylsulfonyloxy)naphthalene-2-sulfonate crude product obtained in Synthesis Example 1, 90 g, was added to the aqueous triphenylsulfonium chloride solution obtained in Synthesis Example 4 and 400 g of dichloromethane, which was stirred for one hour at room temperature. The organic layer was separated, washed with 400 g of water, and concentrated in vacuum. The residue, 130 g, was purified by recrystallization from diethyl ether, obtaining the end product, triphenylsulfonium 6-(4′-methylphenylsulfonyloxy)naphthalene-2-sulfonate as crystals in an amount of 100 g (yield 79%).