5-Decene → 1-Hexene

HRID 2122091

反応式

HRID 2122091 の反応式
C([O:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH:12]=[CH:13][CH2:14][CH2:15][CH2:16][CH3:17])=O.[CH3:18][CH2:19][CH2:20][CH2:21][CH:22]=[CH:23]CCCC.C(O)CCCCCCCC=C>>[CH2:4]([OH:3])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH:12]=[CH:13][CH2:14][CH2:15][CH2:16][CH3:17].[CH2:18]=[CH:19][CH2:20][CH2:21][CH2:22][CH3:23]

参加物

5

実験手順

FIG. 18 shows a synthesis of 9-tetradecenyl formate, in which 5-decene is cross-metathesized with 9-decenol to produce 9-tetradecenol while 1-hexene is removed from the reaction under vacuum, and in which the metathesis product, 9-tetradecenol, is reacted with formyl acetate.

出典と根拠

ORDレコード
ord-ef8fdae9e8bc4d2c91fc059af82b804c
出典データセット
uspto-grants-2004_02
特許番号
US06696597B2

関連ノート

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