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Dichloromethane → 4-Octyl-biphenyl-4'-terephthalic acid chloride
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dichloromethane | HCID 6344 | — |
| 反応物 | Terephthaloyl chloride | HCID 7488 | — |
| 反応物 | 2-Dimethylaminopyridine | HCID 21885 | — |
| 反応物 | 4'-Octyl-[1,1'-biphenyl]-4-ol | HCID 14047211 | — |
| 溶媒 | Triethylamine | HCID 8471 | — |
| 生成物 | 4-Octyl-biphenyl-4'-terephthalic acid chloride | HCID 131719017 | — |
反応手順
To a solution of 4-hydroxy-4'-octylbiphenyl (0.5 g) and terephthaloyl chloride (0.36 g) in about dichloromethane (30 ml) was added drop by drop triethylamine (0.2 g). To the solution was added dimethylaminopyridine (0.013 g) and the mixture was stirred at the room temperature for 10 hours to obtain the titled compound.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05424005 |
| 出典データセット | uspto-grants-1995_06 |
| ORD ID | ord-2394b2dec9d049a3b2e5b53f9d321778 |
| 出典メモ | uspto-grants-1995_06 |