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Benzoyl chloride → 1,2-Dibenzoyl-1-(tert-butyl)hydrazine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Benzoyl chloride | HCID 7412 | — |
| 反応物 | Tert-butylhydrazine ethanedioate(1:1) | HCID 269219 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 溶媒 | Hexane | HCID 8058 | — |
| 溶媒 | Sodium Hydroxide | HCID 14798 | — |
| 生成物 | 1,2-Dibenzoyl-1-(tert-butyl)hydrazine | HCID 86307 | 15% |
反応手順
The 1,1-dimethylethylhydrazine oxalate (2 g) was dissolved in toluene and neutralized with 50% aqueous sodium hydroxide. To this solution was added benzoyl chloride (4.02 g) and sodium hydroxide (50% Aq. solution) (2.45 g) at 25° C. The reaction mixture was warmed to room temperature and stirred 3 hours. The mixture was diluted with hexane and filtered to afford the product as a white solid (0.5 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05424333 |
| 出典データセット | uspto-grants-1995_06 |
| ORD ID | ord-086b219308224dd4b83325a657c1c1e7 |
| 出典メモ | uspto-grants-1995_06 |