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Toluene → N'-t-butyl-N-(thiobenzoyl)-N'-(3-toluoyl)hydrazine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Toluene | HCID 1140 | — |
| 反応物 | 3-Methylbenzoyl chloride | HCID 74375 | — |
| 反応物 | N'-t-butyl-N-(thiobenzoyl)hydrazine | HCID 19367775 | — |
| 触媒 | Sodium Hydroxide | HCID 14798 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | N'-t-butyl-N-(thiobenzoyl)-N'-(3-toluoyl)hydrazine | HCID 15294606 | — |
反応手順
N'-t-butyl-N-(thiobenzoyl)hydrazine (ca. 1 g), m-toluoyl chloride (approx. 0.7 g) and 50% aqueous sodium hydroxide (6 drops) were mixed in 1 ml water and 10 ml toluene at 23° C. After stirring for 3 hours, ether-hexane was added and the product was isolated by filtration (0.25 g): m.p. 165°-168° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05424333 |
| 出典データセット | uspto-grants-1995_06 |
| ORD ID | ord-f6788d9e4e0e4d4f842feb17a5154dc4 |
| 出典メモ | uspto-grants-1995_06 |